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[Data] Research Institute of Chemical Reaction Mechanisms, Delamination Mechanism of Heterogeneous Material Interfaces 1

We will introduce a case that elucidates the differences in linear expansion coefficients of PET and PEN films with similar main skeletal structures and the mechanisms that produce these differences.

Although they are different materials, if they have similar molecular structures, there is potential for the development and expansion of composite products due to their compatibility and similar properties. However, while they are similar, there are also pitfalls. For example, differences in linear expansion rates can cause strain and displacement at their interface, leading to delamination in many cases. This document presents a case study that clarifies the differences in linear expansion rates between PET and PEN films, which have similar main chain structures, and the mechanisms that produce these differences. [Contents] - About materials PET and PEN - XPS analysis (comparison of bonding states) - TMA analysis (comparison of linear expansion rates) - Data analysis *For more details, please refer to the PDF document or feel free to contact us.

  • Analytical Equipment and Devices
  • XPS analysis device

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Interference peak removal process in quantitative analysis

X-ray photoelectron spectroscopy (XPS)

In XPS analysis, in addition to the photoelectron peaks used for evaluation, photoelectron peaks from other orbitals and Auger peaks from X-ray excitation are also detected. Depending on the combination of elements, these sub-peaks can overlap with the target peak and interfere with the evaluation. *Typically, a strong photoelectron peak emitted from an inner shell level close to the outer shell is used. In the quantitative calculations of XPS analysis, the removal of such interfering peaks is primarily performed using the following two methods: 1. Removal using sensitivity coefficient ratios 2. Removal using waveform separation

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Evaluation of the oxidation state of titanium oxide (TiOx)

We will also introduce examples of comparative evaluations of various oxidation states of titanium dioxide!

We would like to introduce our evaluation of the oxidation state of titanium oxides (TiOx). In the XPS analysis of titanium oxides, it is possible to investigate the oxidation state from the peak positions, spectral shapes, and satellite positions of the core levels and valence band spectra. In the attached PDF document, we provide examples of comparative evaluations of various oxidation states of titanium oxide, so please take a look. 【Features】 ■ It is possible to investigate the oxidation state from the peak positions, spectral shapes, and satellite positions of the core levels and valence band spectra. *For more details, please download the PDF or feel free to contact us.

  • Other analysis and evaluation services
  • XPS analysis device

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